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Issue 31, 2007
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Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes

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Abstract

Catalytic dehydrogenation of R2NHBH3 (R = Me, H) promoted by a family of bis(cyclopentadienyl)titanium and bis(indenyl)zirconium compounds is reported; structure–reactivity relationships as a function of cyclopentadienyl and indenyl substituents have been examined.

Graphical abstract: Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes

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Publication details

The article was received on 02 Apr 2007, accepted on 26 May 2007 and first published on 11 Jun 2007


Article type: Communication
DOI: 10.1039/B704941B
Citation: Chem. Commun., 2007,0, 3297-3299
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    Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes

    D. Pun, E. Lobkovsky and P. J. Chirik, Chem. Commun., 2007, 0, 3297
    DOI: 10.1039/B704941B

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