Issue 27, 2007
From the journal:

Chemical Communications

Tricarbonylmanganese(i)–lysozyme complex: a structurally characterized organometallic protein†

Mathieu Razavet,a   Vincent Artero,*a   Christine Cavazza,*b   Yohan Oudart,a   Colette Lebrun,c   Juan Carlos Fontecilla-Campsb  and  Marc Fontecavea  

* Corresponding authors

a Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France; CNRS, UMR 5249, France; CEA, DSV/iRTSV, 17 rue des Martyrs, F-38054 Grenoble Cedex 9, France
E-mail: vincent.artero@cea.fr
Fax: 0033 438789124
Tel: 0033 438789106

b Laboratoire de Cristallographie et Cristallogénèse des Protéines, Institut de Biologie Structurale «Jean-Pierre Ebel», UMR CNRS/UJF/CEA 5075, 41 rue Jules Horowitz, F-38027 Grenoble Cedex 1, France
E-mail: christine.cavazza@ibs.fr
Fax: 0033 438785122
Tel: 0033 438785904

c Laboratoire de Reconnaissance Ionique et Chimie de Coordination, UMR CNRS/UJF/CEA E3, 17 rue des Martyrs, F-38054 Grenoble Cedex 9, France

Abstract

The reaction of the new and structurally characterized covalent {Mn(CO)3(H2O)2}+–lysozyme adduct with NiS4 and NiN2S2 complexes generates binuclear Ni–Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)2} intermediate during maturation of [NiFe] hydrogenases is discussed.

Graphical abstract: Tricarbonylmanganese(i)–lysozyme complex: a structurally characterized organometallic protein

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Article information

DOI
https://doi.org/10.1039/B703887A
Article type
Communication
Submitted
14 Mar 2007
Accepted
11 May 2007
First published
11 Jun 2007

Chem. Commun., 2007, 2805-2807

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Tricarbonylmanganese(I)–lysozyme complex: a structurally characterized organometallic protein

M. Razavet, V. Artero, C. Cavazza, Y. Oudart, C. Lebrun, J. C. Fontecilla-Camps and M. Fontecave, Chem. Commun., 2007, 2805 DOI: 10.1039/B703887A

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