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Issue 32, 2007
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Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

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Abstract

Density functional (DFT) calculations, high-temperature electron paramagnetic resonance (EPR) and transmission electron microscopy (TEM) results suggest that thermal homolysis of C59HN involves a remarkably stable intermediate C59N–C59HN˙ structure characterised by charge redistribution from a C59N˙ radical to a bonded C59HN.

Graphical abstract: Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

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Publication details

The article was received on 13 Mar 2007, accepted on 10 May 2007 and first published on 15 Jun 2007


Article type: Communication
DOI: 10.1039/B703766J
Citation: Chem. Commun., 2007,0, 3386-3388
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    Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

    D. Arčon, M. Pregelj, P. Cevc, G. Rotas, G. Pagona, N. Tagmatarchis and C. Ewels, Chem. Commun., 2007, 0, 3386
    DOI: 10.1039/B703766J

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