A stable electrode for high-potential, electrocatalytic O2 reduction based on rational attachment of a blue copper oxidase to a graphite surface

Christopher F. Blanford; Rachel S. Heath; Fraser A. Armstrong

doi:10.1039/B703114A

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Chemical Communications

Issue 17, 2007

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A stable electrode for high-potential, electrocatalytic O₂ reduction based on rational attachment of a blue copper oxidase to a graphite surface

Christopher F. Blanford , Rachel S. Heath and Fraser A. Armstrong

Chem. Commun., 2007, 1710-1712

DOI: 10.1039/B703114A
Received 01 Mar 2007, Accepted 19 Mar 2007
First published on the web 03 Apr 2007

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Attachment of substrate-like anthracene based units to the surface of pyrolytic graphite greatly enhances the adsorption of high-potential fungal laccases, ‘blue’ Cu enzymes that catalyse the four-electron reduction of O₂, providing a stable cathode for enzymatic biological fuel cells and electrochemical studies.

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Chemical Communications

A stable electrode for high-potential, electrocatalytic O₂ reduction based on rational attachment of a blue copper oxidase to a graphite surface

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