Photophysical properties and tunable colour changes of silica single layers doped with lanthanide(III) complexes

Lidia Armelao; Gregorio Bottaro; Silvio Quici; Marco Cavazzini; Maria Concetta Raffo; Francesco Barigelletti; Gianluca Accorsi

doi:10.1039/B702238G

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Chemical Communications

Issue 28, 2007

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Photophysical properties and tunable colour changes of silica single layers doped with lanthanide(III) complexes

Lidia Armelao , Gregorio Bottaro , Silvio Quici , Marco Cavazzini , Maria Concetta Raffo , Francesco Barigelletti and Gianluca Accorsi

Chem. Commun., 2007, 2911-2913

DOI: 10.1039/B702238G
Received 12 Feb 2007, Accepted 09 Mar 2007
First published on the web 23 Mar 2007

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Abstract
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Highly stable Eu(III) and Tb(III) complexes, emitting in the red and green visible regions, respectively, have been anchored onto a single SiO₂ transparent layer, yielding ca. 40 nm thick films; this allows high loading of tailored proportions of the red and green emitters within the films and results in highly uniform and easily colour-tunable luminescent layers.

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Details of film preparation and spectroscopic measurements
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Lidia Armelao
Gregorio Bottaro
Silvio Quici
Marco Cavazzini
Maria Concetta Raffo
Francesco Barigelletti
Gianluca Accorsi

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Chemical Communications

Photophysical properties and tunable colour changes of silica single layers doped with lanthanide(III) complexes

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