Icosahedral galloxane clusters

Robert M. McKinlay; Scott J. Dalgarno; Peter J. Nichols; Stavroula Papadopoulos; Jerry L. Atwood; Colin L. Raston

doi:10.1039/B700984D

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Chemical Communications

Issue 23, 2007

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Icosahedral galloxane clusters

Robert M. McKinlay , Scott J. Dalgarno , Peter J. Nichols , Stavroula Papadopoulos , Jerry L. Atwood and Colin L. Raston

Chem. Commun., 2007, 2393-2395

DOI: 10.1039/B700984D
Received 22 Jan 2007, Accepted 23 Feb 2007
First published on the web 15 Mar 2007

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Abstract
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Hydrolysis of ‘tris(aryl or alkyl)gallium(III)’ species results in the formation of spheroidal dodecameric galloxane mixed oxide–hydroxide clusters, and shows that the gallium centres and associated residual alkyl/aryl groups are arranged at the polyhedral vertices of pseudo-icosahedra.

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General procedure, syntheses and spectral data for new compounds
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Articles By

Robert M. McKinlay
Scott J. Dalgarno
Peter J. Nichols
Stavroula Papadopoulos
Jerry L. Atwood
Colin L. Raston

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Chemical Communications

Icosahedral galloxane clusters

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