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Issue 18, 2007
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Synthesis of two diastereomeric C1–C22 fragments of spirastrellolide A

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Abstract

The optimisation of a synthetic strategy towards the ABC segment of the cytotoxic macrolide spirastrellolide A is reported, together with its application to the synthesis of two diastereomeric C1–C22 fragments for stereochemical correlation purposes with a putative spirastrellolide degradation product.

Graphical abstract: Synthesis of two diastereomeric C1–C22 fragments of spirastrellolide A

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Publication details

The article was received on 18 Jan 2007, accepted on 29 Jan 2007 and first published on 14 Feb 2007


Article type: Communication
DOI: 10.1039/B700827A
Citation: Chem. Commun., 2007,0, 1852-1854
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    Synthesis of two diastereomeric C1–C22 fragments of spirastrellolide A

    I. Paterson, E. A. Anderson, S. M. Dalby, J. Genovino, J. H. Lim and C. Moessner, Chem. Commun., 2007, 0, 1852
    DOI: 10.1039/B700827A

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