Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes

Oriana Esposito; Alexandra K. de K. Lewis; Peter B. Hitchcock; Stephen Caddick; F. Geoffrey N. Cloke

doi:10.1039/B700671C

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Chemical Communications

Issue 11, 2007

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Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes

Oriana Esposito , Alexandra K. de K. Lewis , Peter B. Hitchcock , Stephen Caddick and F. Geoffrey N. Cloke

Chem. Commun., 2007, 1157-1159

DOI: 10.1039/B700671C
Received 16 Jan 2007, Accepted 29 Jan 2007
First published on the web 14 Feb 2007

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Abstract
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The transamination of alkylpalladium halide N-heterocyclic carbene complexes has enabled the isolation of products that reveal interesting insights into the factors which might be barriers to the development of a palladium-catalysed alkyl–amination reaction.

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Oriana Esposito
Alexandra K. de K. Lewis
Peter B. Hitchcock
Stephen Caddick
F. Geoffrey N. Cloke

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Chemical Communications

Synthesis and reactivity of alkylpalladium N-heterocyclic carbene complexes

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