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Issue 14, 2007
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A reductase-mimicking thiourea organocatalyst incorporating a covalently bound NADH analogue: efficient 1,2-diketone reduction with in situ prosthetic group generation and recycling

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Abstract

A new class of bifunctional organocatalyst promotes the chemoselective reduction of diketone electrophiles at catalytic loadings in the presence of an inorganic co-reductant.

Graphical abstract: A reductase-mimicking thiourea organocatalyst incorporating a covalently bound NADH analogue: efficient 1,2-diketone reduction with in situ prosthetic group generation and recycling

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Publication details

The article was received on 02 Jan 2007, accepted on 04 Jan 2007 and first published on 30 Jan 2007


Article type: Communication
DOI: 10.1039/B618792G
Citation: Chem. Commun., 2007,0, 1421-1423
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    A reductase-mimicking thiourea organocatalyst incorporating a covalently bound NADH analogue: efficient 1,2-diketone reduction with in situ prosthetic group generation and recycling

    B. Procuranti and S. J. Connon, Chem. Commun., 2007, 0, 1421
    DOI: 10.1039/B618792G

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