Issue 16, 2007
From the journal:

Chemical Communications

Structural variations in bimetallic sodium–magnesium and sodium–zinc ketimides, and a sodium–zinc alkide–alkoxide–amide: connections to ring-stacking, ring-laddering, and inverse crown concepts†

William Clegg,a   Sophie H. Dale,a   David V. Graham,b   Ross W. Harrington,a   Eva Hevia,b   Lorna M. Hogg,b   Alan R. Kennedyb  and  Robert E. Mulvey*b  

* Corresponding authors

a School of Natural Sciences (Chemistry), Newcastle University, Newcastle upon Tyne, UK

b WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

The first sodium–magnesium and sodium–zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium–zinc heterotrianionic alkide–alkoxide–amide adopts a third type of structure with a stepped ladder motif.

Graphical abstract: Structural variations in bimetallic sodium–magnesium and sodium–zinc ketimides, and a sodium–zinc alkide–alkoxide–amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

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Article information

DOI
https://doi.org/10.1039/B618609B
Article type
Communication
Submitted
20 Dec 2006
Accepted
16 Jan 2007
First published
06 Feb 2007

Chem. Commun., 2007, 1641-1643

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Structural variations in bimetallic sodium–magnesium and sodium–zinc ketimides, and a sodium–zinc alkide–alkoxide–amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

W. Clegg, S. H. Dale, D. V. Graham, R. W. Harrington, E. Hevia, L. M. Hogg, A. R. Kennedy and R. E. Mulvey, Chem. Commun., 2007, 1641 DOI: 10.1039/B618609B

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