Fluoride ion complexation by a cationic borane in aqueous solution

Min Hyung Lee; Tomohiro Agou; Junji Kobayashi; Takayuki Kawashima; François P. Gabbaï

doi:10.1039/B616814K

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Chemical Communications

Issue 11, 2007

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Fluoride ion complexation by a cationic borane in aqueous solution

Min Hyung Lee , Tomohiro Agou , Junji Kobayashi , Takayuki Kawashima and François P. Gabbaï

Chem. Commun., 2007, 1133-1135

DOI: 10.1039/B616814K
Received 16 Nov 2006, Accepted 20 Jan 2007
First published on the web 06 Feb 2007

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Abstract
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The phosphonium borane [p-Mes₂B(C₆H₄)PMePh₂]⁺ complexes fluoride in water containing 10% methanol with a binding constant of 1.0(±0.1) × 10³ M⁻¹ to afford the zwitterion p-Mes₂FB(C₆H₄)PMePh₂.

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Min Hyung Lee
Tomohiro Agou
Junji Kobayashi
Takayuki Kawashima
François P. Gabbaï

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Chemical Communications

Fluoride ion complexation by a cationic borane in aqueous solution

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