A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

Santokh S. Tandon; Scott D. Bunge; Laurence K. Thompson

doi:10.1039/B612795A

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Chemical Communications

Issue 8, 2007

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A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

Santokh S. Tandon , Scott D. Bunge and Laurence K. Thompson

Chem. Commun., 2007, 798-800

DOI: 10.1039/B612795A
Received 05 Sep 2006, Accepted 01 Nov 2006
First published on the web 23 Nov 2006

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2,6-Diformyl-4-methylphenol and 1,3-diamino-2-hydroxypropane template condense in the presence of Cu(NO₃)₂ and azide to produce a 3 : 3 macrocyclic ring containing an unprecedented grouping of seven copper(II) ions within the macrocyclic cavity, with the seventh metal completing a body-centred heptanuclear lattice.

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Chemical Communications

A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

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