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Issue 35, 2007
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Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

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Abstract

The preparation and molecular structure of a W24+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π–M2δ–ligand π conjugation.

Graphical abstract: Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

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Publication details

The article was received on 12 Jun 2007, accepted on 06 Jul 2007 and first published on 07 Aug 2007


Article type: Communication
DOI: 10.1039/B708746B
Citation: Chem. Commun., 2007, 3652-3654
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    Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

    M. V. Barybin, M. H. Chisholm, N. J. Patmore, R. E. Robinson and N. Singh, Chem. Commun., 2007, 3652
    DOI: 10.1039/B708746B

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