Issue 26, 2007
From the journal:

Chemical Communications

The racemate cage. Influence of p1,n1salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid

Goffredo Rosini,*a   Valerio Borzatta,b   Francesca Boschi,a   Gabriele Candido,b   Emanuela Marottaa  and  Paolo Righia  

* Corresponding authors

a Dipartimento di Chimica Organica “A. Mangini”, Alma Mater Studiorum – Università di Bologna, V.le del Risorgimento 4, Bologna, Italy
E-mail: goffredo.rosini@unibo.it
Fax: +39 051 2093654

b ENDURA SpA, V.le Pietramellara 5, Bologna, Italy

Abstract

The occurrence of p1,n1salt when accompanied by substrate self-association can have profound effects on enantiomer separation processes of non-racemic mixtures, impeding the complete recovery of the major enantiomer through formation of an inescapable racemate cage.

Graphical abstract: The racemate cage. Influence of p1,n1salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid

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Article information

DOI
https://doi.org/10.1039/B703506C
Article type
Communication
Submitted
08 Mar 2007
Accepted
03 Apr 2007
First published
19 Apr 2007

Chem. Commun., 2007, 2717-2719

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The racemate cage. Influence of p1,n1salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid

G. Rosini, V. Borzatta, F. Boschi, G. Candido, E. Marotta and P. Righi, Chem. Commun., 2007, 2717 DOI: 10.1039/B703506C

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