A novel three-dimensional heterometallic compound: templated assembly of the unprecedented planar “Na⊂[Cu4]” metalloporphyrin-like subunits

Yan-Feng Yue; Bing-Wu Wang; En-Qing Gao; Chen-Jie Fang; Cheng He; Chun-Hua Yan

doi:10.1039/B618296H

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A novel three-dimensional heterometallic compound: templated assembly of the unprecedented planar “Na⊂[Cu₄]” metalloporphyrin-like subunits†

Yan-Feng Yue,^a Bing-Wu Wang,^a En-Qing Gao,^b Chen-Jie Fang,^a Cheng He^a and Chun-Hua Yan*^a

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* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications & PKU-HKU Joint Lab on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing, China
E-mail: yan@pku.edu.cn
Fax: +86 10 6275 4179
Tel: +86 10 6275 4179

^b Shanghai Key Lab of Green Chemistry and Chemical Process Greening, East China Normal University, Shanghai, China

Abstract

A 3D heterometallic compound, [Cu₄Na₄(TzDC)₄(H₂O)₇]_n (H₃TzDC = 1,2,3-triazole-4,5-dicarboxylic acid), which contains unprecedented planar “Na⊂[Cu₄]” metalloporphyrin-like subunits, was synthesized by hydrothermal reactions involving in situ formation of the ligand and templated assembly of the metalloporphyrin-like subunits.

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Article information

DOI: https://doi.org/10.1039/B618296H
Article type: Communication
Submitted: 14 Dec 2006
Accepted: 05 Feb 2007
First published: 21 Feb 2007

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Chem. Commun., 2007, 2034-2036

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A novel three-dimensional heterometallic compound: templated assembly of the unprecedented planar “Na⊂[Cu₄]” metalloporphyrin-like subunits

Y. Yue, B. Wang, E. Gao, C. Fang, C. He and C. Yan, Chem. Commun., 2007, 2034 DOI: 10.1039/B618296H

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Chemical Communications