Issue 10, 2007
From the journal:

Chemical Communications

Photodimerization of acenaphthylene within a nanocapsule: excited state lifetime dependent dimer selectivity†

Lakshmi S. Kaanumallea  and  V. Ramamurthy*a  

* Corresponding authors

a Department of Chemistry, University of Miami, Coral Gables, FL
E-mail: murthy1@miami.edu
Fax: +1 305 284 4571
Tel: +1 305 284 1534

Abstract

Direct excitation of acenaphthylene molecules included in a syn fashion within the octa acid nanocapsule dimerizes quantitatively to a syn dimer, and upon triplet sensitization, yields both syn and anti dimers probably by reacting within and outside the capsule.

Graphical abstract: Photodimerization of acenaphthylene within a nanocapsule: excited state lifetime dependent dimer selectivity

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Article information

DOI
https://doi.org/10.1039/B615937K
Article type
Communication
Submitted
02 Nov 2006
Accepted
23 Nov 2006
First published
14 Dec 2006

Chem. Commun., 2007, 1062-1064

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Photodimerization of acenaphthylene within a nanocapsule: excited state lifetime dependent dimer selectivity

L. S. Kaanumalle and V. Ramamurthy, Chem. Commun., 2007, 1062 DOI: 10.1039/B615937K

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