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Issue 6, 2007
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Experimental and theoretical evidence of the first Au(I)⋯Bi(III) interaction

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Abstract

Complex [Au(C6F5)2][Bi(C6H4CH2NMe2-2)2] 1 displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%).

Graphical abstract: Experimental and theoretical evidence of the first Au(i)⋯Bi(iii) interaction

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Publication details

The article was received on 15 Sep 2006, accepted on 25 Oct 2006 and first published on 15 Nov 2006


Article type: Communication
DOI: 10.1039/B613365G
Citation: Chem. Commun., 2007,0, 571-573
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    Experimental and theoretical evidence of the first Au(I)⋯Bi(III) interaction

    E. J. Fernández, A. Laguna, J. M. López-de-Luzuriaga, M. Monge, M. Nema, M. E. Olmos, J. Pérez and C. Silvestru, Chem. Commun., 2007, 0, 571
    DOI: 10.1039/B613365G

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