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Issue 3, 2007
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Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

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Abstract

Novel rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks were synthesized and the complexes were used as catalysts in rhodium-catalyzed hydrosilylation of α,β-unsaturated ketones to show high 1,4-adduct selectivity.

Graphical abstract: Rhodium(i) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

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Publication details

The article was received on 30 Aug 2006, accepted on 29 Sep 2006 and first published on 25 Oct 2006


Article type: Communication
DOI: 10.1039/B612385F
Citation: Chem. Commun., 2007,0, 269-271
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    Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

    H. Sato, T. Fujihara, Y. Obora, M. Tokunaga, J. Kiyosu and Y. Tsuji, Chem. Commun., 2007, 0, 269
    DOI: 10.1039/B612385F

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