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Issue 3, 2007
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π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

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Abstract

Reaction of LnCl3 with KSeAr* in thf afforded the unsolvated, alkane-soluble complexes LnCl(SeAr*)2 (Ln = Nd, Pr; Ar* = 2,6-Trip2C6H3; Trip = 2,4,6-iPr3C6H2) in which the rare-earth metal cations show additional η6-π-coordination by two flanking arene rings.

Graphical abstract: π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

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Publication details

The article was received on 25 Aug 2006, accepted on 10 Oct 2006 and first published on 26 Oct 2006


Article type: Communication
DOI: 10.1039/B612182A
Citation: Chem. Commun., 2007,0, 275-277
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    π-Bonding encapsulation in aryl-substituted lanthanide selenolates: monomeric compounds with apparent low-coordinate metal atoms

    S. Hauber and M. Niemeyer, Chem. Commun., 2007, 0, 275
    DOI: 10.1039/B612182A

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