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Issue 11, 2006
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Enantioselective construction of quaternary carbon centre catalysed by bifunctional organocatalyst

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Abstract

The bifunctional thioureatertiary amine derivatives of simple chiral diamines serve as highly enantioselective catalysts for the Michael addition of α-substituted cyanoacetates to vinyl sulfones, giving an efficient protocol for the construction of an all-carbon substituted quaternary stereocentre.

Graphical abstract: Enantioselective construction of quaternary carbon centre catalysed by bifunctional organocatalyst

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Publication details

The article was received on 25 Apr 2006, accepted on 02 May 2006 and first published on 09 May 2006


Article type: Communication
DOI: 10.1039/B605871J
Citation: Org. Biomol. Chem., 2006,4, 2097-2099
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    Enantioselective construction of quaternary carbon centre catalysed by bifunctional organocatalyst

    T. Liu, J. Long, B. Li, L. Jiang, R. Li, Y. Wu, L. Ding and Y. Chen, Org. Biomol. Chem., 2006, 4, 2097
    DOI: 10.1039/B605871J

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