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Issue 8, 2006
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Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure

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Abstract

The skeletal rearrangement of bicyclo[2.2.2]lactones, involving a mild and chemoselective palladium-catalysed translocation key-step, provides an efficient and diastereoselective access to synthetically useful bicyclo[3.3.0]lactones.

Graphical abstract: Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure

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Publication details

The article was received on 21 Dec 2005, accepted on 26 Feb 2006 and first published on 08 Mar 2006


Article type: Communication
DOI: 10.1039/B518121F
Citation: Org. Biomol. Chem., 2006,4, 1464-1467
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    Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure

    J. Liao, N. Maulide, B. Augustyns and I. E. Markó, Org. Biomol. Chem., 2006, 4, 1464
    DOI: 10.1039/B518121F

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