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Issue 5, 2006
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A novel supported Katsuki-type (salen)Mn complex for asymmetric epoxidation

Keith Smith,*a  Chia-Hui Liua  and  Gamal A. El-Hitia 
Author affiliations

* Corresponding authors

a Centre for Clean Chemistry, Department of Chemistry, University of Wales Swansea, Singleton Park, Swansea, UK

Abstract

We have successfully prepared an unsymmetrical analogue of a Katsuki-type salen ligand having a hydroxyalkyl group at the 6-position of just one of the binaphthyl units in the ligand, and also several Mn(III) complexes; these complexes have been attached to a polymer by an ester link and such polymer catalysts have been shown to be highly enantioselective and recoverable catalysts for the epoxidation of 1,2-dihydronaphthalene.

Graphical abstract: A novel supported Katsuki-type (salen)Mn complex for asymmetric epoxidation

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Publication details

The article was received on 12 Dec 2005, accepted on 20 Jan 2006 and first published on 01 Feb 2006


Article type: Paper
DOI: 10.1039/B517611P
Citation: Org. Biomol. Chem., 2006,004, 917-927
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    A novel supported Katsuki-type (salen)Mn complex for asymmetric epoxidation

    K. Smith, C. Liu and G. A. El-Hiti, Org. Biomol. Chem., 2006, 004, 917
    DOI: 10.1039/B517611P

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