Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multisubstituted pyrrolidines

Yan-Biao Kang; Yong Tang; Xiu-Li Sun

doi:10.1039/B512195G

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Organic & Biomolecular Chemistry

Issue 2, 2006

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Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multisubstituted pyrrolidines

Yan-Biao Kang , Yong Tang and Xiu-Li Sun

Org. Biomol. Chem., 2006, 4, 299-301

DOI: 10.1039/B512195G
Received 31 Aug 2005, Accepted 14 Nov 2005
First published on the web 06 Dec 2005

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Abstract
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A tandem ring-opening–cyclization reaction of cyclopropanes with imines in the presence of 5 mol% of scandium triflate was developed for the highly diastereoselective synthesis of multisubstituted pyrrolidines.

Abstract from Methods in Organic Synthesis 2006

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Abstract from Catalysts & Catalysed Reactions 2006

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Supplementary Info

Spectral data, ¹H and ¹³C NMR spectra for all new compounds and stereochemical assignments
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Organic & Biomolecular Chemistry

Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multisubstituted pyrrolidines

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