Molecular tectonics: on the formation of tubular coordination networks

Guillaume Laugel; Ernest Graf; Mir Wais Hosseini; Jean-Marc Planeix; Nathalie Kyritsakas

doi:10.1039/B607982M

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New Journal of Chemistry

Issue 9, 2006

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Molecular tectonics: on the formation of tubular coordination networks

Guillaume Laugel , Ernest Graf , Mir Wais Hosseini , Jean-Marc Planeix and Nathalie Kyritsakas

New J. Chem., 2006, 30, 1340-1346

DOI: 10.1039/B607982M
Received 05 Jun 2006, Accepted 24 Jul 2006
First published on the web 14 Aug 2006

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Abstract
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Upon combining the organic tecton based on the [1,1,1,1]metacyclophane bearing four pyridine groups with silver cation, a tubular coordination network formed by double bridging of consecutive macrocycles by metal centres is obtained and structurally characterised in the solid state by an X-ray diffraction method. The same tecton when combined with HgCl₂ leads to the formation of a doubly interpenetrated 2-D coordination framework.

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Guillaume Laugel
Ernest Graf
Mir Wais Hosseini
Jean-Marc Planeix
Nathalie Kyritsakas

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New Journal of Chemistry

Molecular tectonics: on the formation of tubular coordination networks

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