Porphyrin based metallamacrocycles

Emmanuel Deiters; Véronique Bulach; Mir Wais Hosseini

doi:10.1039/B606041M

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New Journal of Chemistry

Issue 9, 2006

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Porphyrin based metallamacrocycles

Emmanuel Deiters , Véronique Bulach and Mir Wais Hosseini

New J. Chem., 2006, 30, 1289-1294

DOI: 10.1039/B606041M
Received 27 Apr 2006, Accepted 21 Jun 2006
First published on the web 18 Jul 2006

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Abstract
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Upon combining 5,10-dipyridyl-15,20-diphenylporphyrin 1 or its copper metallated complex 2 with metal halides (MX₂: M = Zn, Cd, Hg; X = I or Br) five [2 + 2] metallamacrocycles of the square type were obtained and structurally characterised in the crystalline phase by X-ray diffraction methods. Whereas the free porphyrin 1 leads to the formation of homobinuclear metallamacrocycles with both CdI₂ and HgI₂, a homotetranuclear metallamacrocycle resulting from the metallation of the porphyrin core is obtained in the presence of ZnI₂. When using the premetallated copper complex 2, two heterotetranuclear metallamacrocycles are generated in the presence of CdI₂ and HgBr₂.

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Porphyrin based metallamacrocycles

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