Molecular tectonics: generation of 1- and 2-D copper coordination networks by positional isomeric tectons based on a phenylenediamine backbone bearing two isonicotinoyl moieties

Jérôme Pansanel; Abdelaziz Jouaiti; Sylvie Ferlay; Mir Wais Hosseini; Jean-Marc Planeix; Nathalie Kyritsakas

doi:10.1039/B600193A

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New Journal of Chemistry

Issue 5, 2006

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Molecular tectonics: generation of 1- and 2-D copper coordination networks by positional isomeric tectons based on a phenylenediamine backbone bearing two isonicotinoyl moieties

Jérôme Pansanel , Abdelaziz Jouaiti , Sylvie Ferlay , Mir Wais Hosseini , Jean-Marc Planeix and Nathalie Kyritsakas

New J. Chem., 2006, 30, 683-688

DOI: 10.1039/B600193A
Received 06 Jan 2006, Accepted 16 Feb 2006
First published on the web 15 Mar 2006

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The combination of three isomeric organic tectons 1–3 based on 1,2-, 1,3- and 1,4-phenylenediamine backbones bearing two isonicotinoyl groups with a Cu(OAc)₂ neutral complex leads to the formation of 1-D and 2-D coordination networks. Whereas for both tectons 1 and 2 the network is generated through the interconnection of the organic moieties by copper dimers of the paddle-wheel type, in the case of 3, the 2-D network is formed by another type of connector, a binuclear copper complex for which the two metal centres adopt an octahedral coordination geometry.

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Jérôme Pansanel
Abdelaziz Jouaiti
Sylvie Ferlay
Mir Wais Hosseini
Jean-Marc Planeix
Nathalie Kyritsakas

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New Journal of Chemistry

Molecular tectonics: generation of 1- and 2-D copper coordination networks by positional isomeric tectons based on a phenylenediamine backbone bearing two isonicotinoyl moieties

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