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Issue 5, 2006
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Molecular tectonics: generation of 1- and 2-D copper coordination networks by positional isomeric tectons based on a phenylenediamine backbone bearing two isonicotinoyl moieties

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Abstract

The combination of three isomeric organic tectons 1–3 based on 1,2-, 1,3- and 1,4-phenylenediamine backbones bearing two isonicotinoyl groups with a Cu(OAc)2 neutral complex leads to the formation of 1-D and 2-D coordination networks. Whereas for both tectons 1 and 2 the network is generated through the interconnection of the organic moieties by copper dimers of the paddle-wheel type, in the case of 3, the 2-D network is formed by another type of connector, a binuclear copper complex for which the two metal centres adopt an octahedral coordination geometry.

Graphical abstract: Molecular tectonics: generation of 1- and 2-D copper coordination networks by positional isomeric tectons based on a phenylenediamine backbone bearing two isonicotinoyl moieties

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Publication details

The article was received on 06 Jan 2006, accepted on 16 Feb 2006 and first published on 15 Mar 2006


Article type: Paper
DOI: 10.1039/B600193A
Citation: New J. Chem., 2006,30, 683-688
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    Molecular tectonics: generation of 1- and 2-D copper coordination networks by positional isomeric tectons based on a phenylenediamine backbone bearing two isonicotinoyl moieties

    J. Pansanel, A. Jouaiti, S. Ferlay, M. W. Hosseini, J. Planeix and N. Kyritsakas, New J. Chem., 2006, 30, 683
    DOI: 10.1039/B600193A

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