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Issue 3, 2006
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Valence shell charge concentrations and the Dewar–Chatt–Duncanson bonding model

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Abstract

Combined experimental and theoretical charge density studies of the complex [Ni(η2-C2H4)dbpe] (dbpe = But2PCH2CH2PBut2), 1, reveal how the location and magnitude of charge concentrations in the valence shell of the metal atom influence the σ- and π-components of the metal–olefin interaction.

Graphical abstract: Valence shell charge concentrations and the Dewar–Chatt–Duncanson bonding model

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Publication details

The article was received on 26 Oct 2005, accepted on 06 Jan 2006 and first published on 03 Feb 2006


Article type: Letter
DOI: 10.1039/B515171F
Citation: New J. Chem., 2006,30, 309-312
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    Valence shell charge concentrations and the Dewar–Chatt–Duncanson bonding model

    W. Scherer, G. Eickerling, D. Shorokhov, E. Gullo, G. S. McGrady and P. Sirsch, New J. Chem., 2006, 30, 309
    DOI: 10.1039/B515171F

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