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Issue 9, 2006
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Chromium based polyatomic interferences on rhodium in ICP-MS

Antoaneta P. Krushevska,a  Ying Zhou,a  V. Ravikumar,a  Young-Jin Kima  and  Joachim Hinrichsb 
Author affiliations

a GE Global Research Center, One Research Circle, Niskayuna, USA

b Thermo Electron (Bremen) GmbH, Hanna-Kunath-Str. 9-11, 28199 Bremen, Germany

Abstract

A previously unknown polyatomic interference for the mono-isotopic element Rh in the presence of a high concentration of chromium is reported in this study. Instrumental parameters were investigated and optimized to minimize the interference. A correction method was established which enabled accurate determination of Rh in the presence of high Cr matrix on a quadrupole ICP-MS. High resolution ICP-MS was used to resolve the interfering species from the Rh signal in order to determine their origin and to validate the established low resolution ICP-MS method.

Graphical abstract: Chromium based polyatomic interferences on rhodium in ICP-MS

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Publication details

The article was received on 15 Feb 2006, accepted on 13 Jul 2006 and first published on 04 Aug 2006


Article type: Paper
DOI: 10.1039/B602266A
Citation: J. Anal. At. Spectrom., 2006,21, 847-855
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    Chromium based polyatomic interferences on rhodium in ICP-MS

    A. P. Krushevska, Y. Zhou, V. Ravikumar, Y. Kim and J. Hinrichs, J. Anal. At. Spectrom., 2006, 21, 847
    DOI: 10.1039/B602266A

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