Issue 42, 2006

Coordination complexes bearing potentially tetradentate phenoxyamine ligands

Abstract

A series of metal complexes containing potentially tetradentate phenoxyamine ligands is described. The ligands are found to bind to main-group metals and first-row transition-metal centres with variable denticity depending upon the requirements of the particular metal centre. Bidentate [Al(III)], tridentate [Mg(II), Ca(II), Zn(II)] and tetradentate [K(I), Cr(III), Fe(II), Co(II)] binding modes have been established unambiguously through single-crystal X-ray structure determinations.

Graphical abstract: Coordination complexes bearing potentially tetradentate phenoxyamine ligands

Supplementary files

Article information

Article type
Paper
Submitted
31 May 2006
Accepted
11 Aug 2006
First published
01 Sep 2006

Dalton Trans., 2006, 5014-5023

Coordination complexes bearing potentially tetradentate phenoxyamine ligands

A. R. F. Cox, V. C. Gibson, E. L. Marshall, A. J. P. White and D. Yeldon, Dalton Trans., 2006, 5014 DOI: 10.1039/B607753F

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