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Issue 42, 2006
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Coordination complexes bearing potentially tetradentate phenoxyamine ligands

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Abstract

A series of metal complexes containing potentially tetradentate phenoxyamine ligands is described. The ligands are found to bind to main-group metals and first-row transition-metal centres with variable denticity depending upon the requirements of the particular metal centre. Bidentate [Al(III)], tridentate [Mg(II), Ca(II), Zn(II)] and tetradentate [K(I), Cr(III), Fe(II), Co(II)] binding modes have been established unambiguously through single-crystal X-ray structure determinations.

Graphical abstract: Coordination complexes bearing potentially tetradentate phenoxyamine ligands

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Publication details

The article was received on 31 May 2006, accepted on 11 Aug 2006 and first published on 01 Sep 2006


Article type: Paper
DOI: 10.1039/B607753F
Citation: Dalton Trans., 2006,0, 5014-5023
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    Coordination complexes bearing potentially tetradentate phenoxyamine ligands

    A. R. F. Cox, V. C. Gibson, E. L. Marshall, A. J. P. White and D. Yeldon, Dalton Trans., 2006, 0, 5014
    DOI: 10.1039/B607753F

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