Issue 24, 2006
From the journal:

Dalton Transactions

Polymeric arrangements of P–Se anions and a first insight into their reactivity†

Weifeng Shi,a   Maryam Shafaei-Fallah,a   Christopher E. Ansona  and  Alexander Rothenberger*ab  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Karlsruhe, Geb. 30.45, Engesserstr. 15a, 76131 Karlsruhe, Germany
E-mail: ar252@chemie.uni-karlsruhe.de

b Institut für Nanotechnologie, Forschungszentrum Karlsruhe GmbH, Postfach 3640, 76021 Karlsruhe, Germany

Abstract

The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)µ-Se]2 with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P–Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3]2− or [PhPSe2Se–SeSe2PPh]2− dianions are observed and the mechanisms of their formation described.

Graphical abstract: Polymeric arrangements of P–Se anions and a first insight into their reactivity

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Article information

DOI
https://doi.org/10.1039/B601704E
Article type
Paper
Submitted
06 Feb 2006
Accepted
20 Mar 2006
First published
06 Apr 2006

Dalton Trans., 2006, 2979-2983

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Polymeric arrangements of P–Se anions and a first insight into their reactivity

W. Shi, M. Shafaei-Fallah, C. E. Anson and A. Rothenberger, Dalton Trans., 2006, 2979 DOI: 10.1039/B601704E

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