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Issue 14, 2006
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Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species

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Abstract

Unsymmetrical functionalization of a discrete α-{SiW12O40} Keggin with two heterometallic building blocks, a Cu(II) dimer and a Cu(II) monomer, results in the formation of [{Cu2(O2CMe)2(5,5′-dimethyl-2,2′-bipy)2}{Cu(5,5′-dimethyl-2,2′-bipy)2}SiW12O40] that displays interesting physical properties.

Graphical abstract: Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(ii) species

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Publication details

The article was received on 03 Jan 2006, accepted on 09 Feb 2006 and first published on 24 Feb 2006


Article type: Communication
DOI: 10.1039/B518316B
Citation: Dalton Trans., 2006, 1712-1714
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    Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species

    C. Ritchie, E. Burkholder, P. Kögerler and L. Cronin, Dalton Trans., 2006, 1712
    DOI: 10.1039/B518316B

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