Issue 44, 2006
From the journal:

Dalton Transactions

Synthesis and characterization of binuclear half-sandwich metal (Co, Ir and Ru) complexes containing ancillary ortho-carborane-1,2-dithiolato ligands

Shuang Liu,a   Jiasheng Zhang,a   Xin Wanga  and  Guo-Xin Jin*a  

* Corresponding authors

a Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, and Key Lab of Molecular Engineering of Polymers of Chinese Ministry of Education, Department of Macromolecular Science, Fudan University, 200433 Shanghai, China
E-mail: gxjin@fudan.edu.cn
Fax: +86-21-65641740
Tel: +86-21-65643776

Abstract

The assembly of soluble, air-stable, binuclear structures, namely {(p-cymene)Ru[S2C2(B10H10)]}2(µ-pyz) (4), {Cp*Co[S2C2(B10H10)]}2(µ-pyz) (5), {Cp*Co[S2C2(B10H10)]}2(µ-bpy) (6), {Cp*Co[S2C2(B10H10)]}2(µ-bpe) (7) and {Cp*Ir[E2C2(B10H10)]}2(µ-bpo) (E = S (8a), Se (8b)), in which organometallic units are bridged by pyridyl-based organic linkers, are synthesized. The complexes have been fully characterized by IR and NMR spectroscopy, as well as elemental analysis. The molecular structures of 4, 5, 6, 7 and 8 are established through X-ray crystallography.

Graphical abstract: Synthesis and characterization of binuclear half-sandwich metal (Co, Ir and Ru) complexes containing ancillary ortho-carborane-1,2-dithiolato ligands

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B608934H
Article type
Paper
Submitted
26 Jun 2006
Accepted
14 Sep 2006
First published
22 Sep 2006

Dalton Trans., 2006, 5225-5230

Permissions

Request permissions

Synthesis and characterization of binuclear half-sandwich metal (Co, Ir and Ru) complexes containing ancillary ortho-carborane-1,2-dithiolato ligands

S. Liu, J. Zhang, X. Wang and G. Jin, Dalton Trans., 2006, 5225 DOI: 10.1039/B608934H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements