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Issue 21, 2006
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Physico-chemical processes in imidazolium ionic liquids

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Among the various properties exhibited by ionic liquids (ILs)—especially those based on the imidazolium cation—their inherent ionic patterns, very low vapour pressure and pronounced self-organization in the solid, liquid and even in the gas phase are particularly interesting since this allows the use of these fluids as alternative and complementary media to classical organic solvents and water in many applications. Hence, reaction paths that involve charge-separated intermediates or transition states are accelerated—by lowering the activation barrier—in the presence of ILs when compared with those performed in classical organic solvents. It is also possible, for example, to observe, by electrochemical methods, transient species (ionic and radical) that are otherwise undetectible in water or in molecular organic solvents and to investigate the interactions and behaviour of molecular, biological and macromolecular species in solution using physical and chemical methods which require special conditions such as high-vacuum, and which have been traditionally limited to solid state chemistry.

Graphical abstract: Physico-chemical processes in imidazolium ionic liquids

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The article was received on 13 Feb 2006, accepted on 13 Mar 2006 and first published on 06 Apr 2006

Article type: Invited Article
DOI: 10.1039/B602046A
Citation: Phys. Chem. Chem. Phys., 2006,8, 2441-2452
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    Physico-chemical processes in imidazolium ionic liquids

    J. Dupont and P. A. Z. Suarez, Phys. Chem. Chem. Phys., 2006, 8, 2441
    DOI: 10.1039/B602046A

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