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Issue 3, 2006
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Time-resolved EPR spectra of the triplet excited states of diaminoacridine guests in polar potassium hydrogen phthalate single crystals

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Abstract

Mixed crystals of potassium hydrogen phthalate containing 3,6-diaminoacridine were photoexcited with visible light and the resulting triplet excited states were analyzed by time resolved EPR spectroscopy. Spectra from discrete growth sectors were compared with powders and polycrystalline glasses prepared at various pHs. The data yield the predominant protonation state and orientation of the triplets in each of a pair of growth sectors bounding the positive and negative ends of the polar crystal.

Graphical abstract: Time-resolved EPR spectra of the triplet excited states of diaminoacridine guests in polar potassium hydrogen phthalate single crystals

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Publication details

The article was received on 15 Jul 2005, accepted on 27 Oct 2005 and first published on 18 Nov 2005


Article type: Paper
DOI: 10.1039/B510076C
Citation: Phys. Chem. Chem. Phys., 2006,8, 379-385
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    Time-resolved EPR spectra of the triplet excited states of diaminoacridine guests in polar potassium hydrogen phthalate single crystals

    M. Bellinazzi, A. Barbon, B. Kahr, J. B. Benedict and M. Brustolon, Phys. Chem. Chem. Phys., 2006, 8, 379
    DOI: 10.1039/B510076C

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