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Issue 8, 2006
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Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks

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Abstract

The synthesis and structural characterization of three new polyoxomolybdenum(V) phosphate frameworks have been achieved by using dimeric {Mo6}2 moieties as inorganic building blocks and protonated organic amines as counter ions. The structure-directing role of the organic cations was investigated and it was shown, that the geometry and the rigidity of the amines as well as their hydrogen bonding capabilities influence the formation of layered or chain-like superstructures.

Graphical abstract: Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(v) phosphate frameworks

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Publication details

The article was received on 12 Apr 2006, accepted on 30 Jun 2006, published on 12 Jul 2006 and first published online on 12 Jul 2006


Article type: Paper
DOI: 10.1039/B605285A
Citation: CrystEngComm, 2006,8, 629-634
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    Influence of organic amines on the self-assembly of hybrid polyoxo-molybdenum(V) phosphate frameworks

    C. Streb, D. Long and L. Cronin, CrystEngComm, 2006, 8, 629
    DOI: 10.1039/B605285A

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