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Issue 40, 2006
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Synthesis of the DEF-bis-spiroacetal of spirastrellolide A exploiting a double asymmetric dihydroxylation/spiroacetalisation strategy

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Abstract

An efficient synthesis of the C26–C40 tricyclic [5,6,6]-bis-spiroacetal segment of the marine macrolide spirastrellolide A has been developed, exploiting a novel double Sharpless asymmetric dihydroxylation/spiroacetalisation sequence.

Graphical abstract: Synthesis of the DEF-bis-spiroacetal of spirastrellolide A exploiting a double asymmetric dihydroxylation/spiroacetalisation strategy

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Publication details

The article was received on 04 Sep 2006, accepted on 06 Sep 2006 and first published on 20 Sep 2006


Article type: Communication
DOI: 10.1039/B612697A
Citation: Chem. Commun., 2006, 4186-4188
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    Synthesis of the DEF-bis-spiroacetal of spirastrellolide A exploiting a double asymmetric dihydroxylation/spiroacetalisation strategy

    I. Paterson, E. A. Anderson, S. M. Dalby, J. H. Lim, P. Maltas and C. Moessner, Chem. Commun., 2006, 4186
    DOI: 10.1039/B612697A

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