Issue 46, 2006
From the journal:

Chemical Communications

Phosphazene base-promoted functionalization of aryltrimethylsilanes†

Koichi Suzawa,a   Masahiro Ueno,a   Andrew E. H. Wheatleyb  and  Yoshinori Kondo*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki Aza Aoba 6-3, Aoba-ku, Sendai 980-8578, Japan
E-mail: ykondo@mail.pharm.tohoku.ac.jp
Fax: +81 22 795 6804
Tel: +81 22 795 6804

b Department Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: aehw2@cam.ac.uk
Fax: +44 1223 336362
Tel: +44 1223 763122

Abstract

The activation of Ar–Si bonds in aryltrimethylsilane was investigated using a catalytic amount of t-Bu-P4 base and selective functionalizations of aryltrimethylsilanes in the absence of strong electron withdrawing groups on the aromatic rings were accomplished.

Graphical abstract: Phosphazene base-promoted functionalization of aryltrimethylsilanes

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Article information

DOI
https://doi.org/10.1039/B611090H
Article type
Communication
Submitted
01 Aug 2006
Accepted
18 Sep 2006
First published
04 Oct 2006

Chem. Commun., 2006, 4850-4852

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Phosphazene base-promoted functionalization of aryltrimethylsilanes

K. Suzawa, M. Ueno, A. E. H. Wheatley and Y. Kondo, Chem. Commun., 2006, 4850 DOI: 10.1039/B611090H

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