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Issue 39, 2006
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Synthesis of propargylic fluorides from allenylsilanes

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Abstract

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

Graphical abstract: Synthesis of propargylic fluorides from allenylsilanes

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Publication details

The article was received on 13 Jul 2006, accepted on 27 Jul 2006 and first published on 23 Aug 2006


Article type: Communication
DOI: 10.1039/B610013A
Citation: Chem. Commun., 2006, 4113-4115
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    Synthesis of propargylic fluorides from allenylsilanes

    L. Carroll, M. C. Pacheco, L. Garcia and V. Gouverneur, Chem. Commun., 2006, 4113
    DOI: 10.1039/B610013A

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