Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 45, 2006
Previous Article Next Article

Template-induced formation of heterobidentate ligands and their application in the asymmetric hydroformylation of styrene

Author affiliations

Abstract

We report the template-induced formation of chelating heterobidentate ligands by the selective self-assembly of two different monodentate ligands on a rigid bis-zinc(II)-salphen template with two identical binding sites; these templated heterobidentate ligands induce much higher enantioselectivities (up to 72% ee) in the rhodium-catalyzed asymmetric hydroformylation of styrene than any of the corresponding homobidentate ligands or non-templated mixed ligand combinations (up to 13% ee).

Graphical abstract: Template-induced formation of heterobidentate ligands and their application in the asymmetric hydroformylation of styrene

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 30 Jun 2006, accepted on 03 Aug 2006 and first published on 15 Aug 2006


Article type: Communication
DOI: 10.1039/B609321C
Citation: Chem. Commun., 2006, 4679-4681
  •   Request permissions

    Template-induced formation of heterobidentate ligands and their application in the asymmetric hydroformylation of styrene

    M. Kuil, P. E. Goudriaan, P. W. N. M. van Leeuwen and J. N. H. Reek, Chem. Commun., 2006, 4679
    DOI: 10.1039/B609321C

Search articles by author