Issue 40, 2006
From the journal:

Chemical Communications

New palladium catalysed reactions of bromoporphyrins: synthesis and crystal structures of nickel(ii) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin†

Louisa J. Esdaile,a   Mathias O. Sengeb  and  Dennis P. Arnold*a  

* Corresponding authors

a Synthesis and Molecular Recognition Program, School of Physical and Chemical Sciences, Queensland University of Technology, G.P.O. Box 2434, Brisbane, Australia
E-mail: d.arnold@qut.edu.au
Fax: +61 7 3864 1804
Tel: +61 7 3864 2482

b School of Chemistry, SFI Tetrapyrrole Laboratory, Trinity College Dublin, Dublin 2, Ireland
E-mail: sengem@tcd.ie
Fax: +353 1 608 8536
Tel: +353 1 608 8537

Abstract

Primary aminoporphyrin, secondary bis(porphyrinyl)amine and hydroxyporphyrin complexes have been isolated and characterised both spectroscopically and crystallographically from the reaction of 5-bromo-10,15,20-triphenylporphyrinatonickel(II) with hydrazine under palladium catalysis.

Graphical abstract: New palladium catalysed reactions of bromoporphyrins: synthesis and crystal structures of nickel(ii) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin

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Article information

DOI
https://doi.org/10.1039/B608365J
Article type
Communication
Submitted
13 Jun 2006
Accepted
26 Jul 2006
First published
23 Aug 2006

Chem. Commun., 2006, 4192-4194

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New palladium catalysed reactions of bromoporphyrins: synthesis and crystal structures of nickel(II) complexes of primary 5-aminoporphyrin, 5,5′-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin

L. J. Esdaile, M. O. Senge and D. P. Arnold, Chem. Commun., 2006, 4192 DOI: 10.1039/B608365J

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