Synthesis of luminescent heterometallic bis-lanthanide complexes via selective, sequential metallation

Matthew S. Tremblay; Dalibor Sames

doi:10.1039/B607949K

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Chemical Communications

Issue 39, 2006

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Synthesis of luminescent heterometallic bis-lanthanide complexes via selective, sequential metallation

Matthew S. Tremblay and Dalibor Sames

Chem. Commun., 2006, 4116-4118

DOI: 10.1039/B607949K
Received 14 Jun 2006, Accepted 20 Jul 2006
First published on the web 13 Sep 2006

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Abstract
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A modular synthetic method for the differential incorporation of two lanthanide ions into a single molecular scaffold is reported; the mixed bimetallic Tb/Eu complex displays an interesting solvent polarity-dependent ratiometric luminescence.

Supplementary Info

Synthetic protocols and characterization; experimental details and additional data for photophysical experiments
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Chemical Communications

Synthesis of luminescent heterometallic bis-lanthanide complexes via selective, sequential metallation

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