Benzoporphyrins via an olefin ring-closure metathesis methodology

Lijuan Jiao; Erhong Hao; Frank R. Fronczek; M. Graça H. Vicente; Kevin M. Smith

doi:10.1039/B607711K

Benzoporphyrins via an olefin ring-closure metathesis methodology

Lijuan Jiao,^a Erhong Hao,^a Frank R. Fronczek,^a M. Graça H. Vicente^a and Kevin M. Smith*^a

* Corresponding authors

^a Department of Chemistry, Louisiana State University, Baton Rouge, USA
E-mail: kmsmith@lsu.edu
Fax: +1 225-578-3458
Tel: +1 225-578-7442

Abstract

A new route to benzoporphyrins is reported in which readily available vicinal dibromoporphyrins are bis-allylated using the Suzuki reaction, cyclized by way of olefin metathesis and finally oxidized to give mono-, di-, or tri-benzoporphyrins.

Supplementary files

Publication details

The article was received on 31 May 2006, accepted on 14 Jul 2006 and first published on 07 Aug 2006

Article type: Communication

DOI: 10.1039/B607711K

Citation: Chem. Commun., 2006,0, 3900-3902

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Benzoporphyrins via an olefin ring-closure metathesis methodology

L. Jiao, E. Hao, F. R. Fronczek, M. G. H. Vicente and K. M. Smith, Chem. Commun., 2006, 0, 3900
DOI: 10.1039/B607711K
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Chemical Communications

Benzoporphyrins via an olefin ring-closure metathesis methodology

Abstract

Supplementary files

Publication details

Benzoporphyrins via an olefin ring-closure metathesis methodology

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