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Issue 31, 2006
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An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet

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Abstract

A disc-like heptanuclear Co(II)-cluster, [Co7(bzp)6(N3)9(CH3O)3]·2ClO4·2H2O (1) (bzp = 2-benzoyl pyridine), mixed-bridged by 3/4 azides1,1 and μ1,1,1) and 1/4 μ1,1,1-methanol, shows slow relaxation at static zero and non-zero fields below 6 K, towards single molecule magnet behavior.

Graphical abstract: An azido-bridged disc-like heptanuclear cobalt(ii) cluster: towards a single-molecule magnet

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Publication details

The article was received on 18 Apr 2006, accepted on 08 Jun 2006 and first published on 26 Jun 2006


Article type: Communication
DOI: 10.1039/B605459E
Citation: Chem. Commun., 2006,0, 3302-3304
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    An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet

    Y. Zhang, W. Wernsdorfer, F. Pan, Z. Wang and S. Gao, Chem. Commun., 2006, 0, 3302
    DOI: 10.1039/B605459E

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