Thermodynamic and kinetic factors in the hydrothermal synthesis of hybrid frameworks: zinc 4-cyclohexene-1,2-dicarboxylates

Clare Lee; Caroline Mellot-Draznieks; Ben Slater; G. Wu; William T. A. Harrison; C. N. R. Rao; Anthony K. Cheetham

doi:10.1039/B603512D

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Chemical Communications

Issue 25, 2006

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Thermodynamic and kinetic factors in the hydrothermal synthesis of hybrid frameworks: zinc 4-cyclohexene-1,2-dicarboxylates

Clare Lee , Caroline Mellot-Draznieks , Ben Slater , G. Wu , William T. A. Harrison , C. N. R. Rao and Anthony K. Cheetham

Chem. Commun., 2006, 2687-2689

DOI: 10.1039/B603512D
Received 21 Mar 2006, Accepted 17 May 2006
First published on the web 31 May 2006

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Experimental and computational studies indicate that the formation of a series of zinc 4-cyclohexene-1,2-dicarboxylates takes place under thermodynamic rather than kinetic control.

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Clare Lee
Caroline Mellot-Draznieks
Ben Slater
G. Wu
William T. A. Harrison
C. N. R. Rao
Anthony K. Cheetham

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Chemical Communications

Thermodynamic and kinetic factors in the hydrothermal synthesis of hybrid frameworks: zinc 4-cyclohexene-1,2-dicarboxylates

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