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Issue 22, 2006
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Hosomi–Sakurai reactions of silacyclic allyl silanes

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Abstract

Substituted silacyclohexenes, generated through silene–diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.

Graphical abstract: Hosomi–Sakurai reactions of silacyclic allyl silanes

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Publication details

The article was received on 22 Feb 2006, accepted on 11 Apr 2006 and first published on 02 May 2006


Article type: Communication
DOI: 10.1039/B602642G
Citation: Chem. Commun., 2006, 2385-2387
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    Hosomi–Sakurai reactions of silacyclic allyl silanes

    J. D. Sellars, P. G. Steel and M. J. Turner, Chem. Commun., 2006, 2385
    DOI: 10.1039/B602642G

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