Issue 20, 2006

Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

Abstract

A chiral diphosphonite, derived from BINOL and with an achiral diphenyl ether backbone, is an excellent ligand for the Ir-catalyzed asymmetric hydrogenation of quinolines; achiral P-ligands serving as possible additives (ee = 73–96%).

Graphical abstract: Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

Article information

Article type
Communication
Submitted
16 Feb 2006
Accepted
28 Mar 2006
First published
13 Apr 2006

Chem. Commun., 2006, 2159-2160

Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites

M. T. Reetz and X. Li, Chem. Commun., 2006, 2159 DOI: 10.1039/B602320G

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