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Issue 19, 2006
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Organic solvent nanofiltration in asymmetric hydrogenation: enhancement of enantioselectivity and catalyst stability by ionic liquids

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Abstract

This communication describes the enhancement of the enantioselectivity and the stability of Ru-BINAP with the ionic liquid trihexyl(tetradecyl)phosphonium chloride (CyPhos101), and the use of organic solvent nanofiltration for the efficient separation of the catalyst and ionic liquid from the hydrogenation product, followed by simultaneous recycling of the catalyst and ionic liquid.

Graphical abstract: Organic solvent nanofiltration in asymmetric hydrogenation: enhancement of enantioselectivity and catalyst stability by ionic liquids

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Publication details

The article was received on 14 Feb 2006, accepted on 28 Mar 2006 and first published on 11 Apr 2006


Article type: Communication
DOI: 10.1039/B602184K
Citation: Chem. Commun., 2006, 2063-2065
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    Organic solvent nanofiltration in asymmetric hydrogenation: enhancement of enantioselectivity and catalyst stability by ionic liquids

    H. Wong, Y. H. See-Toh, F. C. Ferreira, R. Crook and A. G. Livingston, Chem. Commun., 2006, 2063
    DOI: 10.1039/B602184K

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