Issue 21, 2006
From the journal:

Chemical Communications

A tripodal sulfur ligand for the selective ruthenium-catalysed hydrogenation of dimethyl oxalate†

Brian Boardman,a   Martin J. Hanton,*a   Hendrik van Rensburga  and  Robert P. Toozea  

* Corresponding authors

a Sasol Technology UK, St Andrews Laboratory, Purdie Building, North Haugh, St Andrews, Fife, UK
E-mail: martin.hanton@uk.sasol.com
Fax: +44(0)1707 383 647
Tel: +44(0)1334 460 830

Abstract

The first example of a catalyst utilising a sulfur-based ligand [MeC(CH2SBu)3] for the selective hydrogenation of dimethyl oxalate to methyl glycolate is reported.

Graphical abstract: A tripodal sulfur ligand for the selective ruthenium-catalysed hydrogenation of dimethyl oxalate

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Article information

DOI
https://doi.org/10.1039/B601216G
Article type
Communication
Submitted
26 Jan 2006
Accepted
13 Apr 2006
First published
02 May 2006

Chem. Commun., 2006, 2289-2291

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A tripodal sulfur ligand for the selective ruthenium-catalysed hydrogenation of dimethyl oxalate

B. Boardman, M. J. Hanton, H. van Rensburg and R. P. Tooze, Chem. Commun., 2006, 2289 DOI: 10.1039/B601216G

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