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Issue 11, 2006
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Stereoselective synthesis of bicyclic lactones by annelation with functionalised orthoesters

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Abstract

An efficient two-step annelation of functionalised orthoesters with trimethylsilyloxyfuran derivatives, which delivers suitably decorated bicyclo[3.n.0]lactones in high overall yields and with complete diastereocontrol of up to three contiguous stereocenters, is reported.

Graphical abstract: Stereoselective synthesis of bicyclic lactones by annelation with functionalised orthoesters

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Publication details

The article was received on 18 Jan 2006, accepted on 30 Jan 2006 and first published on 14 Feb 2006


Article type: Communication
DOI: 10.1039/B600677A
Citation: Chem. Commun., 2006,0, 1200-1202
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    Stereoselective synthesis of bicyclic lactones by annelation with functionalised orthoesters

    N. Maulide and I. E. Markó, Chem. Commun., 2006, 0, 1200
    DOI: 10.1039/B600677A

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