Issue 17, 2006
From the journal:

Chemical Communications

Synthesis and structural characterization of the first metal organic thallium antimonide

Stephan Schulz,*a   Florian Thomasb  and  Martin Niegerc  

* Corresponding authors

a Department Chemie, Universität Paderborn, Warburger Str. 100, J6.214, Paderborn, Germany
E-mail: stephan.schulz@upb.de
Fax: +49 5251 603423
Tel: +49 5251 602493

b BASF AG, Carl-Bosch-Str. 38, Ludwigshafen, Germany
E-mail: florian.thomas@basf.com
Tel: +49 621 6056970

c Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Str. 1, Bonn, Germany
E-mail: nieger@joyx.joensuu.fi
Tel: +49 228 735823

Abstract

The first metal organic thallium antimonide, the heterocycle [Me2TlSb(SiMe3)2]3, was synthesized by reaction of [Me2AlSb(SiMe3)2]3 with the Lewis acid–base adduct dmap-TlMe3 (dmap = 4-dimethylaminopyridine). The analogous TlBi heterocycle [Me2TlBi(SiMe3)2]3 couldn't be isolated due to its limited thermal stability in solution.

Graphical abstract: Synthesis and structural characterization of the first metal organic thallium antimonide

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Article information

DOI
https://doi.org/10.1039/B518072D
Article type
Communication
Submitted
20 Dec 2005
Accepted
10 Mar 2006
First published
20 Mar 2006

Chem. Commun., 2006, 1860-1861

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Synthesis and structural characterization of the first metal organic thallium antimonide

S. Schulz, F. Thomas and M. Nieger, Chem. Commun., 2006, 1860 DOI: 10.1039/B518072D

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